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Article
Author(s)
BoucarDiouf, Waly Diallo, DaoudaNdoye, BocarTraoréandMamadouSidibé
Full-Text PDF XML 127 Views
DOI:10.17265/2162-5263/2024.06.006
Affiliation(s)
Département de ChimieLaboratoire de ChimieMinérale et Analytique, Faculté des Sciences et Techniques, UniversitéCheikh Anta Diop de Dakar, Dakar 5005, Sénégal
ABSTRACT
Threenewmaleate
compoundshavebeensynthesizedandstudiedbyinfrared,25MgNMR (Nuclear Magnetic
Resonance) SpectroscopyandUV
(Ultraviolet)-visiblespectroscopies.Thesuggestedstructuresforthethree complexes
arediscretewithNH-Clhydrogenbonds.Themaleateanionismonochelating (compound 1 and 2)
and bichelating(compound 3). Theenvironmenttin (IV)
and magnesium centerare octahedral andthe zinc center environment is tetrahedral.In all the suggested structures, when
extrahydrogen bonds are considered, supramolecular architectures are obtained.
KEYWORDS
Discretestructures,hydrogenbonds,monochelating,bichetating, octahedralortetrahedralenvironments, maleate, supramolecular.
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