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This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License
Article
Three Selenate New Organotin (IV) and Magnesium Chloride Adducts: Synthesis and Spectroscopic Study
Author(s)
BoucarDiouf, Waly Diallo, DaoudaNdoye, BogouNdiaye, Mamadou Ba and MamadouSidibé
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DOI:10.17265/2162-5263/2024.06.007
Affiliation(s)
Département de ChimieLaboratoire de ChimieMinérale et Analytique, Faculté des Sciences et Techniques, UniversitéCheikh Anta Diop de Dakar, Dakar 5005, Sénégal
ABSTRACT
By allowing H2SeO4,Cy2NH,
CyNH2 or Bz2NH to react respectively with SnPh3Cl
(in methanol), SnPh2Cl2 (in water + methanol) and MgCl2·6H2O (in methanol) inspecific ratios,
the studied complexes are obtained. The suggested structures arediscrete and
polymer, the environment of the tin center being trans trigonal bipyramidal(compound
1), tetrahedral (compound 2) and
octahedral (compound 3), the anionsbehaving as a bidentate selenate.
KEYWORDS
Bidentate, discrete structures,SnPhCl3,SnPh2Cl2 or MgCl2·6H2Oreact, selenate, infinite chain hydrogen bonds, monochelatingmonodentate, trigonal bipyramidal or tetrahedral environments, C2V symmetry, magnesium.
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